Spin bath mediated long-lived coherent oscillations of NV centers in diamond

Decoherence is the biggest bottleneck in all quantum technologies. For nitrogen-vacancy (NV) centers in diamond, the loss of coherence is caused by the electron and nuclear spin bath of the diamond lattice. Here, we demonstrate that the spin bath - that typically causes decoherence - entangles the spin states of the NV electron and the host ¹⁴N nucleus. The many-body interaction between the ¹⁴N nucleus - electron - bath spins at an energy level anti-crossing occurring for an applied magnetic field orientation perpendicular to the NV axis is responsible for this effect. This is observed experimentally on NV ensembles via electron spin-echo measurements, where the echo envelope is modulated at the frequency of a ¹⁴N nuclear spin transition. Using numerical simulations, we show that the spin bath coupling to the NV centers is essential for observing this modulation. Due to the zero first-order Zeeman effect at the anti-crossing, the observed oscillations have long spin-echo coherence times, 2--3 times those at the parallel magnetic field orientation. The oscillation frequency is highly stable and robust against environmental fluctuations. These findings provide new opportunities for fundamental studies of many-body physics and quantum sensing.