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Quantum Chemistry

Spectroscopic investigation of spin zero homonuclear and heteronuclear molecules

arXiv

Authors: Nagalakshmi A. Rao, B. A. Kagali

Year

2007

Paper ID

50518

Status

Preprint

Abstract Read

~2 min

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Abstract

In the present article, we introduce a model to investigate the energy spectrum of a relativistic rotor by considering the Klein-Gordon Hamiltonian. Rotational spectral lines are a signature of homonuclear and heteronuclear systems and play a key role in understanding diatomic molecules. We show that the energy-correction term arising due to unequal masses influences the line separation. Determining the rotational constant enables one to calculate the moment of inertia and bond length of the molecule.

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In the present article, we introduce a model to investigate the energy spectrum of a relativistic rotor by considering the Klein-Gordon Hamiltonian.

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References & Citation Signals

[1] DOI https://doi.org/arXiv:0704.2759 [2] arXiv https://arxiv.org/abs/0704.2759 [3] Publisher https://arxiv.org/abs/0704.2759

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