A criterion for an effective discretization of a continuous Schrödinger spectrum using a pseudostate basis

We consider a Hamiltonian hat H with a (partially) continuous spectrum and examine the zero-overlap condition which involves the projection onto exact continuum eigenstates of a set of pseudostates obtained from the diagonalization of hat H in a finite basis of square-integrable functions. For each projected pseudostate the condition implies the occurrence of zeros at all energies that correspond to the pseudo-continuum matrix eigenvalues, except for the eigenenergy associated with that pseudostate. This feature was observed for the Coulomb continuum represented in a Laguerre basis [M. McGovern et al., Phys. Rev. A 79, 042707 (2009)] and later explained using special properties of the Laguerre functions [I. B. Abdurakhmanov et al., J. Phys. B 44, 075204 (2011)]. We establish that a sufficient condition for the zero-overlap condition to occur is that the image space of the operator hat Q hat H hat P, where hat P is the projection operator onto the subspace spanned by the basis and hat Q = hat 1 - hat P its complement, has dimension one. We show that the condition is met for the one-dimensional free-particle problem by a basis of harmonic oscillator eigenstates and for the Coulomb problem by a Laguerre basis, thus offering an alternative proof for the latter case. The zero-overlap condition ensures that in, e.g., an ionizing collision or laser-atom interaction process, transition probabilities obtained from the projection of a time-propagated pseudostate-expanded system wave function onto eigenstates of hat H are asymptotically stable.