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Quantum Simulation
Enantiodetection in a cavity QED setup with finite chiral molecules
arXiv
Authors: Xiang Guo, Xiaojun Zhang, Yong Li, Zhihai Wang
Year
2025
Paper ID
17219
Status
Preprint
Abstract Read
~2 min
Abstract Words
102
Citations
N/A
Abstract
We investigate enantiodetection for both a single cyclic three-level chiral molecule and finite ensembles of such molecules by monitoring the steady-state intracavity photon number in a cavity-QED platform. Our scheme exploits the intrinsic global π-phase difference between opposite enantiomers to engineer destructive and/or constructive interference pathways, enabling a direct readout of enantiomeric excess with an error below 5\%. To capture mesoscopic many-molecule effects beyond mean field while avoiding brute-force master-equation simulations, we employ a generalized discrete truncated Wigner approximation, which is well suited for systems with many yet finite molecules. These results pave the way for implementing enantiodetection in realistic quantum-optical settings.
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- We investigate enantiodetection for both a single cyclic three-level chiral molecule and finite ensembles of such molecules by monitoring the steady-state intracavity photon...
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