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Influence of N-substituent and solvent on internal conversion in 1-aminonaphthalenes.

PubMed
Authors: Sun X, Wen ZC, Jiang YB

Year

2007

Paper ID

12656

Status

Peer-reviewed

Abstract Read

~2 min

Abstract Words

64

Citations

5

Abstract

N-Methyl-N-methoxycarbonylmethyl-1-aminonaphthalene (MMAN) and N,N-dimethoxycarbonylmethyl-1-aminonaphthalene (DCAN) were synthesized and their fluorescence and absorption spectra in solvents of varied polarity were investigated and compared to those of 1-dimethylaminonaphthylene (DMAN). The data were discussed in terms of the N-substitution effects on the internal conversion (IC). Results showed that the IC was enhanced when the N-methyl group in DMAN was replaced by N-CH2CO2CH3.

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  • N-Methyl-N-methoxycarbonylmethyl-1-aminonaphthalene (MMAN) and N,N-dimethoxycarbonylmethyl-1-aminonaphthalene (DCAN) were synthesized and their fluorescence and absorption...

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References & Citation Signals

[1] DOI https://doi.org/10.1016/j.saa.2006.11.017 [2] Publisher https://pubmed.ncbi.nlm.nih.gov/17331798/

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