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ENDOR evidence for the quantum exchange of the methylene protons.

PubMed
Authors: Herak JN

Year

2008

Paper ID

12638

Status

Peer-reviewed

Abstract Read

~2 min

Abstract Words

72

Citations

0

Abstract

ENDOR spectroscopy was used for studying methylene proton couplings in the 6-yl (or H-addition) radical in a single crystal of 1-methyluracil at 4.2K. The two methylene protons were magnetically equivalent in all crystal (radical) orientations in the magnetic field, indicating proton quantum exchange. The two protons compose magnetically single entity with spin I=1. The observed small ENDOR line splittings of about 0.60MHz agree well with the theoretical expectations for such a system.

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  • ENDOR spectroscopy was used for studying methylene proton couplings in the 6-yl (or H-addition) radical in a single crystal of 1-methyluracil at 4.2K.

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