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Quantum Thermodynamics

Physical-Work Fluctuation Relations from Accessible Quantum Macrostates

arXiv
Authors: Borhan Ahmadi

Year

2026

Paper ID

78644

Status

Preprint

Abstract Read

~2 min

Abstract Words

128

Citations

N/A

Abstract

Jarzynski's equality recovers an equilibrium free-energy difference from nonequilibrium work trajectories, but its exponential average can converge very slowly because rare trajectories carry large weight. We show that coarse thermodynamic information measured at the nonequilibrium endpoint can reduce this sampling burden while keeping the same microscopic trajectories and the same free-energy target. The endpoint mean energy and a coarse spatial record define a maximum-entropy state and select one member of an exact family of fluctuation relations. That physically selected member provides an exact statistical control for the ordinary Jarzynski estimator, even when the final energy and retained record do not commute. In a finite Bose--Hubbard system, this control substantially lowers the finite-confidence sampling cost, while a small controlled departure from exact endpoint matching produces a square-root information--sampling tradeoff.

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  • Jarzynski's equality recovers an equilibrium free-energy difference from nonequilibrium work trajectories, but its exponential average can converge very slowly because rare...

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