Nonlinear collective dynamics and microwave comb generation in a diamond maser

Optically pumped room temperature masers are a promising platform for driven dissipative spin photon physics beyond steady state emission. Here we observe a sequence of dynamical thresholds in a room temperature nitrogen vacancy diamond maser as the optical pump is increased above the conventional masing threshold. The first threshold yields narrow-line continuous wave emission, while a second threshold produces a periodic train of microwave pulses whose repetition rate generates a frequency comb spectrum. At higher pump power, a third threshold gives rise to pulses with an oscillatory, frequency chirped decay. Time-resolved measurements link the comb directly to self-pulsing dynamics and Fourier analysis of individual bursts reveals a broad distribution of frequencies consistent with collective spin-resonator dynamics in an inhomogeneously broadened ensemble. These results establish the diamond maser as a room temperature platform for nonlinear nonequilibrium light matter dynamics and microwave comb generation.