Eigenframe Synchronization in Disordered Driven Quantum Ensembles

Periodic driving underlies many forms of quantum control, including spin-based quantum sensing. However, in an ensemble sensor, one waveform must act on spins with different detunings, drive amplitudes, hyperfine environments, and local fields. Existing robust-control approaches to such disorder are usually framed in terms of coherence, effective Hamiltonians, filter functions, or refocusing. Here we identify a complementary geometric requirement for collective ensemble Floquet control: disorder realizations must share a common Floquet eigenframe. When this condition is met, initialization, protection, signal coupling, and readout are defined in one dressed basis, so the ensemble responds as a collective Floquet sensor rather than as an average over inequivalent driven members. We make this condition measurable with an eigenvector-based synchronization order parameter and a complementary fragmentation metric that quantify the alignment and spread of Floquet quantization axes across the ensemble. As one realization of this framework, we use a continuous counterdiabatic Floquet drive to derive synchronization criteria and predict resonance-governed breakdown at the first two low-order commensurabilities between the engineered Floquet gap and the drive modulation, with detuning and amplitude disorder producing distinct breakdown channels. Experiments on a nitrogen-vacancy (NV) ensemble in diamond verify the synchronized regime through long-lived collective oscillations, a two-dimensional disorder-robustness map, and breakdown resonances that shift with the modulation rate. Finally, we demonstrate a harmonic-free continuous-drive AC magnetometry protocol whose collective single-tone response is enabled by the synchronized Floquet eigenframe. These results establish Floquet eigenframe synchronization as a measurable condition for disorder-resilient collective control and quantum sensing.