Benchmarking Atomic Ionization Driven by Strong Quantum Light

The recently available high-intensity quantum light pulses provide novel tools for controlling light-matter interactions. However, the rigor of the theoretical frameworks currently used to describe the interaction of strong quantum light with atoms and molecules remains unverified. Here, we establish a rigorous benchmark by solving the fully quantized time-dependent Schrödinger equation for an atom exposed to bright squeezed vacuum light. Our ab initio simulations reveal a critical limitation of the widely used Q-representation: although it accurately reproduces the total photoelectron spectrum after tracing over photon states, it completely fails to capture the electron-photon joint energy spectrum. To overcome this limitation, we develop a general theoretical framework based on the Feynman path integral that properly incorporates the electron-photon quantum entanglement. Our results provide both quantitative benchmarks and fundamental theoretical insights for the emerging field of strong-field quantum optics.