Quantum spin coherence in halogen-modified Cr₇Ni molecular nanomagnets

Among the factors determining the quantum coherence of the spin in molecular magnets is the presence and the nature of nuclear spins in the molecule. We have explored modifying the nuclear spin environment in Cr₇Ni-based molecular nanomagnets by replacing hydrogen atoms with deuterium or the halogen atoms, fluorine or chlorine. We find that the spin coherence, studied at low temperatures by pulsed electron spin resonance, is modified by a range of factors, including nuclear spin and magnetic moment, changes in dynamics owing to nuclear mass, and molecular morphology changes.