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Partitioning of the Electron Correlation Energy

arXiv
Authors: Eric Ouma Jobunga

Year

2017

Paper ID

44059

Status

Preprint

Abstract Read

~2 min

Abstract Words

95

Citations

N/A

Abstract

Electron-electron correlation forms the basis of difficulties encountered in many-body problems. Accurate treatment of the correlation problem is likely to unravel some nice physical properties of matter embedded in this correlation. In an effort to tackle this many-body problem, an exact partition function for the correlation energy between two interacting states is proposed in this study. Using this partition function, a model potential for a two-electron system is derived. The model potential can accurately reproduce the singlet states of a singly excited neutral helium atom with one of its electrons frozen in the 1s orbital.

Why This Paper Matters

  • This paper contributes to the Quantum Simulation research area in the Quantum Articles archive.
  • It adds a 2017 reference point for readers tracking recent quantum research.
  • Electron-electron correlation forms the basis of difficulties encountered in many-body problems.

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