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Open Quantum Systems Decoherence Quantum Chemistry

All-optical hyperpolarization of electron and nuclear spins in diamond

arXiv
Authors: Ben L. Green, Ben G. Breeze, Gregory J. Rees, John V. Hanna, Jyh-Pin Chou, Viktor Ivády, Adam Gali, Mark E. Newton

Year

2016

Paper ID

42980

Status

Preprint

Abstract Read

~2 min

Abstract Words

92

Citations

N/A

Abstract

Low thermal polarization of nuclear spins is a primary sensitivity limitation for nuclear magnetic resonance. Here we demonstrate optically pumped (microwave-free) nuclear spin polarization of 13C and 15N in 15N-doped diamond. 15N polarization enhancements up to -2000 above thermal equilibrium are observed in the paramagnetic system Ns0. Nuclear spin polarization is shown to diffuse to bulk 13C with NMR enhancements of -200 at room temperature and -500 at 240 K, enabling a route to microwave-free high-sensitivity NMR study of biological samples in ambient conditions.

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  • This paper contributes to the Quantum Chemistry research area in the Quantum Articles archive.
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  • Low thermal polarization of nuclear spins is a primary sensitivity limitation for nuclear magnetic resonance.

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