Individual solid-state nuclear spin qubits with coherence exceeding seconds

The ability to coherently control and read out qubits with long coherence times in a scalable system is a crucial requirement for any quantum processor. Nuclear spins in the solid state have shown great promise as long-lived qubits. Control and readout of individual nuclear spin qubit registers has made major progress in the recent years using individual electron spin ancilla addressed either electrically or optically. Here, we present a new platform for quantum information processing, consisting of ¹⁸³W nuclear spin qubits adjacent to an Er³⁺ impurity in a CaWO₄ crystal, interfaced via a superconducting resonator and detected using a microwave photon counter at 10mK. We study two nuclear spin qubits with T₂^* of 0.8(2)s and 1.2(3)s, T₂ of 3.4(4)s and 4.4(6) s, respectively. We demonstrate single-shot quantum non-demolition readout of each nuclear spin qubit using the Er³⁺ spin as an ancilla. We introduce a new scheme for all-microwave single- and two-qubit gates, based on stimulated Raman driving of the coupled electron-nuclear spin system. We realize single- and two-qubit gates on a timescale of a few milliseconds, and prepare a decoherence-protected Bell state with 88% fidelity and T₂^* of 1.7(2)s. Our results are a proof-of-principle demonstrating the potential of solid-state nuclear spin qubits as a promising platform for quantum information processing. With the potential to scale to tens or hundreds of qubits, this platform has prospects for the development of scalable quantum processors with long-lived qubits.