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Towards an understanding of dipole-dipole interactions in nonlocal media
arXiv
Authors: L. Inácio, A. Kurumbail, S. K. Panja, I. Brevik, M. Boström
Year
2025
Paper ID
36201
Status
Preprint
Abstract Read
~2 min
Abstract Words
133
Citations
N/A
Abstract
We commence our study with review of dispersion interactions in electrolytes. We then reflect on how background media change atom-atom excited-state systems. To highlight the impact of nonlocal media, such as salt solutions, we predict that a new contribution to the resonance interaction energy emerges in a form propto e-κrm D ρ/ρ. Here κrm D is the Debye length and ρ is the distance between the atoms. This contribution vanishes at zero temperature, where a new term proportional to 1/ρ4 (similar to free space) occurs. This new term is dampened by the electrolyte at large distances, causing it to decrease much faster, proportional to 1/ρ7. The long-range electrolyte-induced resonance interaction at finite temperature may, in addition to the dominating van der Waals attraction which goes as $1/ρ6$, take part in the molecular formation of biological fluids.
Why This Paper Matters
- This paper contributes to the Quantum Chemistry research area in the Quantum Articles archive.
- It adds a 2025 reference point for readers tracking recent quantum research.
- We commence our study with review of dispersion interactions in electrolytes.
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