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Anomalous non-additive dispersion interactions in systems of three one-dimensional wires

arXiv
Authors: Alston J. Misquitta, Ryo Maezono, Neil D. Drummond, Anthony J. Stone, Richard J. Needs

Year

2013

Paper ID

33324

Status

Preprint

Abstract Read

~2 min

Abstract Words

150

Citations

N/A

Abstract

The non-additive dispersion contribution to the binding energy of three one-dimensional (1D) wires is investigated using wires modelled by (i) chains of hydrogen atoms and (ii) homogeneous electron gases. We demonstrate that the non-additive dispersion contribution to the binding energy is significantly enhanced compared with that expected from Axilrod-Teller-Muto-type triple-dipole summations and follows a different power-law decay with separation. The triwire non-additive dispersion for 1D electron gases scales according to the power law d-β, where d is the wire separation, with exponents β\(rs\) smaller than 3 and slightly increasing with rs from 2.4 at rs = 1 to 2.9 at rs=10, where rs is the density parameter of the 1D electron gas. This is in good agreement with the exponent β=3 suggested by the leading-order charge-flow contribution to the triwire non-additivity, and is a significantly slower decay than the sim d-7 behaviour that would be expected from triple-dipole summations.

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  • The non-additive dispersion contribution to the binding energy of three one-dimensional (1D) wires is investigated using wires modelled by (i) chains of hydrogen atoms and (ii)...

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