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Quantum Chemistry

Analytical study of level crossings in the Stark-Zeeman spectrum of ground state OH

arXiv
Authors: N. Cawley, Z. Howard, M. Kleinert, M. Bhattacharya

Year

2013

Paper ID

32742

Status

Preprint

Abstract Read

~2 min

Abstract Words

96

Citations

N/A

Abstract

The ground electronic, vibrational and rotational state of the OH molecule is currently of interest as it can be manipulated by electric and magnetic fields for experimental studies in ultracold chemistry and quantum degeneracy. Based on our recent exact solution of the corresponding effective Stark-Zeeman Hamiltonian, we present an analytical study of the crossings and avoided crossings in the spectrum. These features are relevant to non-adiabatic transitions, conical intersections and Berry phases. Specifically, for an avoided crossing employed in the evaporative cooling of OH, we compare our exact results to those derived earlier from perturbation theory.

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  • The ground electronic, vibrational and rotational state of the OH molecule is currently of interest as it can be manipulated by electric and magnetic fields for experimental...

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References & Citation Signals

[1] DOI https://doi.org/arXiv:1309.3204 [2] arXiv https://arxiv.org/abs/1309.3204 [3] Publisher https://arxiv.org/abs/1309.3204

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