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Open Quantum Systems Decoherence Quantum Chemistry

Emergence of Molecular Chirality by Vibrational Raman Scattering

arXiv
Authors: Farhad Taher Ghahramani, Afshin Shafiee

Year

2013

Paper ID

31889

Status

Preprint

Abstract Read

~2 min

Abstract Words

74

Citations

N/A

Abstract

In this study, we apply the monitoring master equation describing decoherence of internal states to an optically active molecule prepared in a coherent superposition of nondegenerate internal states interacting with thermal photons at low temperatures. We use vibrational Raman scattering theory up to the first chiral-sensitive contribution, i.e., the mixed electric-magnetic interaction, to obtain scattering amplitudes in terms of molecular polarizability tensors. The resulting density matrix is used to obtain elastic decoherence rates.

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  • In this study, we apply the monitoring master equation describing decoherence of internal states to an optically active molecule prepared in a coherent superposition of...

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