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Polymorphism-dependent room-temperature phosphorescence of a persulfurated benzene.

PubMed
Authors: d'Agostino S, Vitale A, Kapadiya Y, Gingras M, Negri F, Ceroni P, Fermi A

Year

2026

Paper ID

30292

Status

Peer-reviewed

Abstract Read

~2 min

Abstract Words

52

Citations

0

Abstract

Persulfurated benzenes are efficient room-temperature phosphorescent materials whose emission strongly depends on solid-state organization. We report two polymorphs (I and II) of exhibiting distinct RTP colors arising from different molecular conformations in the crystal lattice. Quantum chemical calculations reveal how conformation and intermolecular interactions govern the nature of the emissive triplet state.

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  • Persulfurated benzenes are efficient room-temperature phosphorescent materials whose emission strongly depends on solid-state organization.

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