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Open Quantum Systems Decoherence
Quantum Chemistry
Enantiomeric excess determination based on nonreciprocal transition induced spectral line elimination
arXiv
Authors: Xun-Wei Xu, Chong Ye, Yong Li, Ai-Xi Chen
Year
2019
Paper ID
14671
Status
Preprint
Abstract Read
~2 min
Abstract Words
86
Citations
N/A
Abstract
The spontaneous emission spectrum of a multi-level atom or molecule with nonreciprocal transition is investigated. It is shown that the nonreciprocal transition can lead to the elimination of a spectral line in the spontaneous emission spectrum. As an application, we show that nonreciprocal transition arises from the phase-related driving fields in chiral molecules with cyclic three-level transitions, and the elimination of a spectral line induced by nonreciprocal transition provides us a method to determine the enantiomeric excess for the chiral molecules without requiring the enantio-pure samples.
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- This paper contributes to the Quantum Chemistry research area in the Quantum Articles archive.
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- The spontaneous emission spectrum of a multi-level atom or molecule with nonreciprocal transition is investigated.
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