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Quantum Thermodynamics

Self-consistent mode-coupling theory for self-diffusion in quantum liquids.

PubMed
Authors: Reichman DR, Rabani E

Year

2001

Paper ID

13191

Status

Peer-reviewed

Abstract Read

~2 min

Abstract Words

84

Citations

N/A

Abstract

A closed, self-consistent equation for the velocity autocorrelation function of a quantum liquid within the framework of a quantum mode-coupling theory is derived. The solution of the quantum generalized Langevin equation requires static input which is generated by an appropriate path-integral Monte Carlo scheme. In order to assess the accuracy of our approach we have studied the self-diffusion process of liquid para-hydrogen at two thermodynamic state points. Quantitative agreement for the self-diffusion constant is obtained in comparison to experimental measurements and other theoretical predictions.

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  • This paper contributes to the Quantum Thermodynamics research area in the Quantum Articles archive.
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  • A closed, self-consistent equation for the velocity autocorrelation function of a quantum liquid within the framework of a quantum mode-coupling theory is derived.

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