Quick Navigation

Overview Topics Abstract Importance Paper Tools References Reactions Discussion Publication Related

Topics

Spin Qubits Silicon Quantum Computing Quantum Device Fabrication Process Engineering Qubit Coherence Noise Stability Characterization Quantum Chemistry

Molybdenum chalcogenobenzimidato complexes: radical synthesis and nitrile extrusion via beta-EPh E = S, Se, and Te elimination.

PubMed
Authors: Mendiratta A, Cummins CC, Kryatova OP, Rybak-Akimova EV, McDonough JE, Hoff CD

Year

2003

Paper ID

12962

Status

Peer-reviewed

Abstract Read

~2 min

Abstract Words

99

Citations

6

Abstract

Molybdenum chalcogenobenzimidates of formula Ph[PhE]C=NMo(N[t-Bu]Ar)(3) Ar = 3,5-C(6H(3)Me(2)) have been obtained by treatment of Mo(N[t-Bu]Ar)(3) sequentially with benzonitrile and 0.5 equiv of PhEEPh E = S, Se, and Te. Molecular structure determinations have been carried out for the S and Se variants. The Te variant extrudes PhCN forming structurally characterized (PhTe)Mo(N[t-Bu]Ar)(3) with facility assessed via stopped-flow kinetic measurements, while the Se and S analogues exhibit increasing stability. Quantum chemical calculations and solution calorimetry have been employed as an aid to interpretation of the PhCN extrusion reaction.

Why This Paper Matters

  • This paper contributes to the Quantum Chemistry research area in the Quantum Articles archive.
  • It adds a 2003 reference point for readers tracking recent quantum research.
  • Molybdenum chalcogenobenzimidates of formula Ph[PhE]C=NMo(N[t-Bu]Ar)(3) Ar = 3,5-C(6H(3)Me(2)) have been obtained by treatment of Mo(N[t-Bu]Ar)(3) sequentially with...

Paper Tools

Become a member to use research tools

Sign in to open papers, visit source links, share, cite, compare, copy DOI links, request category corrections, and build your reading list.

Become a member Sign in
Publisher Share Cite This Paper Copy URL Compare Copy DOI Add to Reading List Category Correction Request

References & Citation Signals

[1] DOI https://doi.org/10.1021/ic035077d [2] Publisher https://pubmed.ncbi.nlm.nih.gov/14686837/

Local Citation Graph (Related-Paper Links)

Current Paper #12962 #68465 Bounding Eigenstate Overlap fro... #68440 Classical State Preparation for... #68437 Transition-state lattice modes ... #68423 Selective Fermi-Level Pinning: ...

External citation index: OpenAlex citation signal • updated 2026-06-11 04:16:07

Community Reactions

Quick sentiment from readers on this paper.

Score: 0
Likes: 0 Dislikes: 0

Sign in to react to this paper.

Discussion & Reviews (Moderated)

Average Rating: 0.0 / 5 (0 ratings)

No written reviews yet.