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Photo-degradation of chlorophenols in the aqueous solution.

PubMed
Authors: Czaplicka M

Year

2006

Paper ID

12761

Status

Peer-reviewed

Abstract Read

~2 min

Abstract Words

93

Citations

267

Abstract

The review presents the chlorophenols photo-degradation kinetics and mechanism in the aquatic environment under UV-vis in the presence of hydroxyl radicals and singlet oxygen. The influence of experimental parameters e.g. pH, dissociation degree, presence of oxidants in solution, number and position of Cl atoms on the quantum yield and reaction rate constant of chlorophenols are discussed. Mechanisms of photolysis, reaction with hydroxyl radicals, singlet oxygen and secondary reactions for mono-, di-, tri-, tetra- and pentachlorophenol are proposed. The pathways for intermediate reactions e.g. dechlorination, oxidation, dimerization for chlorophenols are also presented.

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  • This paper contributes to the Quantum Chemistry research area in the Quantum Articles archive.
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  • The review presents the chlorophenols photo-degradation kinetics and mechanism in the aquatic environment under UV-vis in the presence of hydroxyl radicals and singlet oxygen.

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References & Citation Signals

[1] DOI https://doi.org/10.1016/j.jhazmat.2005.10.039 [2] Publisher https://pubmed.ncbi.nlm.nih.gov/16325999/

Local Citation Graph (Related-Paper Links)

Current Paper #12761 #68465 Bounding Eigenstate Overlap fro... #68440 Classical State Preparation for... #68437 Transition-state lattice modes ... #68423 Selective Fermi-Level Pinning: ...

External citation index: OpenAlex citation signal • updated 2026-06-11 07:02:26

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