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Synthesis and characterization of a novel high luminescent gold-2-mercapto-1-methyl-imidazole complex.

PubMed
Authors: Cardone G, Carotenuto G, Conte P, Alonzo G

Year

2011

Paper ID

12263

Status

Peer-reviewed

Abstract Read

~2 min

Abstract Words

75

Citations

6

Abstract

Synthesis and characterization of a new gold-2-mercapto-1-methyl imidazole are reported. This new organic material shows an extraordinary fluorescence activity (superfluorescence) up to 220°C with an unusual quantum yield of 0.2. Both fluorescence and NMR spectroscopy were applied to understand the behavior of the gold-2-mercapto-1-methylimidazole complex. Results suggest that the superfluorescence activity can be attributed to the shrinking of the HOMO-LUMO band gap energy following complexation of the organic imidazole system with gold.

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  • This paper contributes to the Quantum Chemistry research area in the Quantum Articles archive.
  • It adds a 2011 reference point for readers tracking recent quantum research.
  • Synthesis and characterization of a new gold-2-mercapto-1-methyl imidazole are reported.

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References & Citation Signals

[1] DOI https://doi.org/10.1002/bio.1260 [2] Publisher https://pubmed.ncbi.nlm.nih.gov/22162452/

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External citation index: OpenAlex citation signal • updated 2026-10-21 21:13:19

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