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Quantum Chemistry

Variational and perturbative approaches to the confined hydrogen atom with a moving nucleus

arXiv

Authors: Francisco M. Fernández, N. Aquino, A. Flores-Riveros

Year

2010

Paper ID

11325

Status

Preprint

Abstract Read

~2 min

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Abstract

We calculate the ground--state energy and other physical properties of the hydrogen atom inside a spherical box with an impenetrable wall. We apply the variational method and perturbation theory and compare both approximate results. We show that the total, kinetic and potential energies for the moving--nucleus model are greater than those for the case in which the nucleus is clamped at the box center.

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We calculate the ground--state energy and other physical properties of the hydrogen atom inside a spherical box with an impenetrable wall.

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References & Citation Signals

[1] DOI https://doi.org/arXiv:1009.2154 [2] arXiv https://arxiv.org/abs/1009.2154 [3] Publisher https://arxiv.org/abs/1009.2154

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